Anyway, this is based on combining ideas from two papers: firstly, Commuting Probabilities of Finite Groups, by Sean Eberhard (thanks to Juan Arias de Reyna for pointing this out to me), and Word-Induced Measures on Compact Groups, by John Wiltshire-Gordon and Gene Kopp.
So, first, let's summarize the first of these papers. If you have a finite group, you can consider the probability that a randomly chosen ordered pair of elements from it commutes. You could then consider the set of all probabilities obtained this way; this is some set of rational numbers between 0 and 1.
In this paper, Eberhard shows that this set is in fact reverse well-ordered! Moreover, this later paper of Browning shows its (reverse) order type is ωω, and that it's closed in (0,1]. Here's my questions:
In particular it likely makes sense to focus on ap for p prime, so you're just counting elements of order p together with the identity. As already mentioned there's at least a starting gap proven for p=2. And having run some numbers with p=2 and p=3... I gotta say they look reverse well-ordered to me. So I'd bet on this simple case being true, at least. (I had thought moreover that the largest probability less than 1 would be 1-1/p+1/p², as occurs with p=2 and p=3 as mentioned above, but this turns out not to be the case; thanks to David Speyer for pointing this out to me. Apparently it's an open problem whether a gap exists for ap in general.))
Note that both for aba-1b-1 and for a², the proof of a gap is simple enough that it works for compact groups too, not just finite groups. Unfortunately the existing gap proof for a³ seems to rely heavily on finiteness. (There are proofs out there for a² that rely on finiteness, but you can do it without it.) (Note that a trivial case is the F2 word "ab", which will again get you ω. More generally this will work for any word a1...an∈Fn for n>0, where the ai are the free generators. But that's kind of a trivial case. (I suppose an even more trivial case would be n=0, where you get 1 as your order type. But...))
(Another trivial variant of the problem is if you restrict to abelian groups, because then your probabilities will always be of the form 1/n (or 0 if you allow compact), since the satisfying tuples will form a subgroup of the Cartesian product. But that doesn't say very much...)
Also a fourth question worth asking: Are these sets closed? For aba-1b-1 this is now proven; could it be true more generally? Well, it actually can't if we restrict to finite groups; it's easy to see that ap can't be closed for p an odd prime (since (p-1)/p is a limit point but not in the set). However, could it be true if we allow compact groups? Then that limit point appears. Not something I'm going to work on, though... (of course, maybe someone's already done it and I don't know!)
(Updates: See blog entries here and here for more on this, and this page for other algebraic structures.)